Hypsochromic Shift
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Hypsochromic Shift

Hypsochromic shift (from ancient Greek ? (upsos) "height"; and chr?ma, "color") is a change of spectral band position in the absorption, reflectance, transmittance, or emission spectrum of a molecule to a shorter wavelength (higher frequency). Because the blue color in the visible spectrum has a shorter wavelength than most other colors, this effect is also commonly called a blue shift.

This can occur because of a change in environmental conditions: for example, a change in solvent polarity will result in solvatochromism. A series of structurally related molecules in a substitution series can also show a hypsochromic shift. Hypsochromic shift is a phenomenon seen in molecular spectra, not atomic spectra - it is thus more common to speak of the movement of the peaks in the spectrum rather than lines.

where is the wavelength of the spectral peak of interest and

For example, ?-acylpyrrole will show a hypsochromic shift of 30-40 nm in comparison with ?-acylpyrroles.

See also

  This article uses material from the Wikipedia page available here. It is released under the Creative Commons Attribution-Share-Alike License 3.0.



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