Spin states when describing transition metal coordination complexes refers to the potential spin configurations of the central metal's d electrons. In many these spin states vary between high-spin and low-spin configurations. These configurations can be understood through the two major models used to describe coordination complexes; crystal field theory and ligand field theory, which is a more advanced version based on molecular orbital theory.
The ? splitting of the d orbitals plays an important role in the electron spin state of a coordination complex. Three factors affect ?: the period (row in periodic table) of the metal ion, the charge of the metal ion, and the field strength of the complex's ligands as described by the spectrochemical series. Only octahedral complexes of first row transition metals adopt high-spin states.
In order for low spin splitting to occur, the energy cost of placing an electron into an already singly occupied orbital must be less than the cost of placing the additional electron into an eg orbital at an energy cost of ?. If the energy required to pair two electrons is greater than the energy cost of placing an electron in an eg, ?, high spin splitting occurs.
If the separation between the orbitals is large, then the lower energy orbitals are completely filled before population of the higher orbitals according to the Aufbau principle. Complexes such as this are called "low-spin" since filling an orbital matches electrons and reduces the total electron spin. If the separation between the orbitals is small enough then it is easier to put electrons into the higher energy orbitals than it is to put two into the same low-energy orbital, because of the repulsion resulting from matching two electrons in the same orbital. So, one electron is put into each of the five d orbitals before any pairing occurs in accord with Hund's rule resulting in what is known as a "high-spin" complex. Complexes such as this are called "high-spin" since populating the upper orbital avoids matches between electrons with opposite spin.
The charge of the metal center plays a role in the ligand field and the ? splitting. The higher the oxidation state of the metal, the stronger the ligand field that is created. In the event that there are two metals with the same d electron configuration, the one with the higher oxidation state is more likely to be low spin than the one with the lower oxidation state. For example, Fe2+ and Co3+ are both d6; however, the higher charge of Co3+ creates a stronger ligand field than Fe2+. All other things being equal, Fe2+ is more likely to be high spin than Co3+.
Ligands also affect the magnitude of ? splitting of the d orbitals according to their field strength as described by the spectrochemical series. Strong-field ligands, such as CN- and CO, increase the ? splitting and are more likely to be low-spin. Weak-field ligands, such as I- and Br- cause a smaller ? splitting and are more likely to be high-spin.
Some octahedral complexes exhibit spin crossover, where the high and low spin states exist is dynamic equilibrium.
The ? splitting energy for tetrahedral metal complexes (four ligands), ?tet is smaller than that for an octahedral complex. Consequently, tetrahedral complexes are almost always high spin Examples of low spin tetrahedral complexes include Fe(2-norbornyl)4, [Co(4-norbornyl)4]+, and the nitrosyl complex Cr(NO)((N(tms)2)3.
Many d8 complexes of the first row metals exist in tetrahedral or square planar geometry. In some cases these geometries exist in measurable equilibria. For example, dichlorobis(triphenylphosphine)nickel(II) has been crystallized in both tetrahedral and square planar geometries.
In terms of d-orbial splitting, ligand field theory (LFT) and crystal field theory (CFT) give similar results. CFT is an older, simpler model that treats ligands as point charges. LFT is more chemical, emphasizes covalent bonding and accommodates pi-bonding explicitly.
In the case of octahedral complexess, the question of high spin vs low spin first arises for d4, since it has more than the 3 electrons to fill the non-bonding d orbitals according to ligand field theory or the stabilized d orbitals according to crystal field splitting.
All complexes of second and third row metals are low-spin.
Generally, the rates of ligand dissociation from low spin complexes are lower than dissociation rates from high spin complexes. In the case of octahedral complexes, electrons in the eg levels are anti-bonding with respect to the metal-ligand bonds. Famous "exchange inert" complexes are octahedral complexes of d3 and low-spin d6 metal ions, illustrated respectfully by Cr3+ and Co3+.