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X-ray Absorption Spectroscopy
Panel of different types of X-ray absorption spectroscopy requiring a synchrotron radiation facility
Figure 1: Transitions that contribute to XAS edges
Figure 2: Three regions of XAS data for the K-edge
X-ray absorption spectroscopy (XAS) is a widely used technique for determining the local geometric and/or electronic structure of matter. The experiment is usually performed at synchrotron radiation facilities, which provide intense and tunable X-ray beams. Samples can be in the gas phase, solutions, or solids.
XAS data is obtained by tuning the photon energy, using a crystalline monochromator, to a range where core electrons can be excited (0.1-100 keV). The edges are, in part, named by which core electron is excited: the principal quantum numbers n = 1, 2, and 3, correspond to the K-, L-, and M-edges, respectively. For instance, excitation of a 1s electron occurs at the K-edge, while excitation of a 2s or 2p electron occurs at an L-edge (Figure 1).
There are three main regions found on a spectrum generated by XAS data which are then thought of as separate spectroscopic techniques (Figure 2):
The absorption threshold determined by the transition to the lowest unoccupied states:
the bound core excitons in insulators with a Lorentzian line-shape (they occur in a pre-edge region at energies lower than the transitions to the lowest unoccupied level);
The X-ray Absorption Near-Edge Structure (XANES) introduced in 1980 and later in 1983, also called NEXAFS (Near-edge X-ray Absorption Fine Structure) which are dominated by core transitions to quasi bound states (multiple scattering resonances) for photoelectrons with kinetic energy in the range from 10 to 150 eV above the chemical potential, called "shape resonances" in molecular spectra since they are due to final states of short life-time degenerate with the continuum with the Fano line-shape. In this range multi-electron excitations and many-body final states in strongly correlated systems are relevant;
In the high kinetic energy range of the photoelectron, the scattering cross-section with neighbor atoms is weak, and the absorption spectra are dominated by EXAFS (Extended X-ray Absorption Fine Structure), where the scattering of the ejected photoelectron of neighboring atoms can be approximated by single scattering events. In 1985, it was shown that multiple scattering theory can be used to interpret both XANES and EXAFS; therefore, the experimental analysis focusing on both regions is now called XAFS.
XAS is a type of absorption spectroscopy from a core initial state with a well defined symmetry; therefore, the quantum mechanical selection rules select the symmetry of the final states in the continuum, which are usually a mixture of multiple components. The most intense features are due to electric-dipole allowed transitions (i.e. ?l = ± 1) to unoccupied final states. For example, the most intense features of a K-edge are due to core transitions from 1s -> p-like final states, while the most intense features of the L3-edge are due to 2p -> d-like final states.