Selenium-79
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Selenium-79
Selenium-79, 79Se
General
Symbol79Se
Namesselenium-79, Se-79
Protons34
Neutrons45
Nuclide data
Natural abundancetrace
Half-life327,000 ± 28,000 y
Decay products79Br
Spin7/2+
Excess energy-75917.46 ± 0.22 keV
Binding energy8695.592 ± 0.003 keV
Decay modes
Decay modeDecay energy (MeV)
Beta decay0.1506
Isotopes of selenium
Complete table of nuclides

Selenium-79 is a radioisotope of selenium present in spent nuclear fuel and the wastes resulting from reprocessing this fuel. It is one of only 7 long-lived fission products. Its yield is low (about 0.04%), as it is near the lower end of the mass range for fission products. Its half-life has been variously reported as 650,000 years, 65,000 years, 1.13 million years, 480,000 years, 295,000 years, 377,000 years and most recently with best current precision, 327,000 years.[1][2]

79Se decays by emitting a beta particle with no attendant gamma radiation. The low specific activity and relatively low energy of its beta particle have been said to limit the radioactive hazards of this isotope.[3]

Performance assessment calculations for the Belgian deep geological repository estimated 79Se may be the major contributor to activity release in terms of becquerels (decays per second), "attributable partly to the uncertainties about its migration behaviour in the Boom Clay and partly to its conversion factor in the biosphere." (p. 169).[4] However, "calculations for the Belgian safety assessments use a half-life of 65 000 years" (p. 177), much less than the currently estimated half-life, and "the migration parameters ... have been estimated very cautiously for 79Se." (p. 179)

Neutron absorption cross sections for 79Se have been estimated at 50 barns for thermal neutrons and 60.9 barns for resonance integral.[5]

Selenium-80 and selenium-82 have higher fission yields, about 20 times the yield of 79Se in the case of uranium-235, 6 times in the case of plutonium-239 or uranium-233, and 14 times in the case of plutonium-241.[6]

Mobility of selenium in the environment

Due to redox-disequilibrium, selenium could be very reluctant to chemical reduction and would be released from the waste (spent fuel or vitrified waste) as soluble selenate, a species not sorbed onto clay minerals. Without solubility limit and retardation for aqueous selenium, the dose of 79Se is comparable to that of 129I. Moreover, selenium is an essential micronutrient for many organisms (protection of cell membrane against oxidative damages) and can be easily bioconcentrated in the food chain. In the presence of nitrate, even reduced forms of selenium could be easily oxidised and mobilised.[7]

Nuclide t Yield Decay
energy
[a 1]
Decay
mode
(Ma) (%)[a 2] (keV)
99Tc 0.211 6.1385 294 ?
126Sn 0.230 0.1084 4050[a 3] ??
79Se 0.327 0.0447 151 ?
93Zr 1.53 5.4575 91
135Cs 2.3 6.9110[a 4] 269 ?
107Pd 6.5 1.2499 33 ?
129I 15.7 0.8410 194
  1. ^ Decay energy is split among ?, neutrino, and ? if any.
  2. ^ Per 65 thermal-neutron fissions of U-235 and 35 of Pu-239.
  3. ^ Has decay energy 380 keV,
    but decay product Sb-126 has decay energy 3.67 MeV.
  4. ^ Lower in thermal reactor because predecessor absorbs neutrons.

References

  1. ^ "Home". Ptb.de. 22 June 2017. Retrieved .
  2. ^ Jörg, G., Bühnemann, R., Hollas, S., Kivel, N., Kossert, K., Van Winckel, S., Lierse v. Gostomski, Ch. Applied Radiation and Isotopes 68 (2010), 2339-2351
  3. ^ "ANL factsheet" (PDF). Ead.anl.gov. Archived from the original (PDF) on 2004-06-15. Retrieved .
  4. ^ Marivoet; et al. (2001). "Safir-2 report" (PDF). Nirond.be. Retrieved .
  5. ^ "Archived copy". Archived from the original on 2011-06-05. Retrieved .CS1 maint: archived copy as title (link)
  6. ^ "Nuclear Data for Safeguards". Nds.iaea.org. Retrieved .
  7. ^ Wright, Winfield G. (1999-07-01). "Oxidation and mobilization of selenium by nitrate in irrigation drainage". J. Environ. Qual. 28 (4): 1182-1187. doi:10.2134/jeq1999.00472425002800040019x. Retrieved .

See also


  This article uses material from the Wikipedia page available here. It is released under the Creative Commons Attribution-Share-Alike License 3.0.

Selenium-79
 



 



 
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