Duralumin (also called duraluminum, duraluminium, duralum, dural(l)ium, or dural) is a trade name for one of the earliest types of age-hardenable aluminium alloys. Its use as a trade name is obsolete, and today the term mainly refers to aluminium-copper alloys, designated as the 2000 series by the International Alloy Designation System (IADS), as with 2014 and 2024 alloys used in airframe fabrication.
In addition to aluminium, the main materials in duralumin are copper, manganese and magnesium. For instance, Duraluminium 2024 consists of 91-95% aluminium, 3.8-4.9% copper, 0.3-0.9% manganese, 1.2-1.8% magnesium, <0.5% iron, <0.5% silicon, <.0.25% zinc, <0.15% titanium, <0.10% chromium and no more than 0.15% of other elements together.
Duralumin was developed by the German metallurgist Alfred Wilm at Dürener Metallwerke AG. In 1903, Wilm discovered that after quenching, an aluminium alloy containing 4% copper would slowly harden when left at room temperature for several days. Further improvements led to the introduction of duralumin in 1909. The name is mainly used in popular science to describe the Al-Cu alloy system, or '2000' series, as designated by the International Alloy Designation System (IADS) originally created in 1970 by the Aluminum Association.
Duralumin, its composition and heat treatment, was openly published in the German scientific literature before World War I. Despite this, it was not adopted beyond Germany until after World War I. Reports of German use during World War I, even in technical journals such as Flight, could still mis-identify its key alloying component as magnesium rather than copper. In the UK there was little interest in its use until after the War.
The earliest known attempt to use duralumin for a heavier-than-air aircraft structure occurred in 1916, when Hugo Junkers first introduced its use in the creation of the Junkers J 3's airframe, a single-engined monoplane "technology demonstrator" that marked the first use of the Junkers trademark duralumin corrugated skinning. Only the covered wings and tubular fuselage framework of the J 3 were ever completed, before the project was abandoned. The slightly later, solely IdFlieg-designated Junkers J.I armoured sesquiplane, known to the factory as the Junkers J 4, had its all-metal wings and horizontal stabilizer made in the same manner as the J 3's wings had been, along with the experimental and airworthy all-duralumin Junkers J 7 single-seat fighter design, which led to the Junkers D.I low-wing monoplane fighter, introducing all-duralumin aircraft structural technology to German military aviation in 1918.
Its first use in aerostatic airframes was in rigid airship frames eventually including all those of the "Great Airship" era of the 1920s and 1930s: the British built R-100, the German passenger Zeppelins LZ 127 Graf Zeppelin, LZ 129 Hindenburg, LZ 130 Graf Zeppelin II, and U.S. Navy airships USS Los Angeles (ZR-3, ex-LZ 126), USS Akron (ZRS-4) and USS Macon (ZRS-5).
Although the addition of copper improves strength, it also makes these alloys susceptible to corrosion. For sheet products, corrosion resistance can be greatly enhanced by metallurgical bonding of a high-purity aluminium surface layer. These sheets are referred to as alclad, and are commonly used by the aircraft industry.
Aluminium alloyed with copper (Al-Cu alloys), which can be precipitation hardened, are designated by the International Alloy Designation System as the 2000 series. Typical uses for wrought Al-Cu alloys include: