Coulomb's law, or Coulomb's inverse-square law, is an experimental law of physics that quantifies the amount of force between two stationary, electrically charged particles. The electric force between charged bodies at rest is conventionally called electrostatic force or Coulomb force. The quantity of electrostatic force between stationary charges is always described by Coulomb's law. The law was first published in 1785 by French physicist Charles-Augustin de Coulomb, and was essential to the development of the theory of electromagnetism, maybe even its starting point, because it was now possible to discuss quantity of electric charge in a meaningful way.
In its scalar form, the law is:
where ke is Coulomb's constant (ke ? ),q1 and q2 are the signed magnitudes of the charges, and the scalar r is the distance between the charges. The force of the interaction between the charges is attractive if the charges have opposite signs (i.e., F is negative) and repulsive if like-signed (i.e., F is positive).
Being an inverse-square law, the law is analogous to Isaac Newton's inverse-square law of universal gravitation, but gravitational forces are always attractive, while electrostatic forces can be attractive or repulsive. Coulomb's law can be used to derive Gauss's law, and vice versa. In the case of a single stationary point charge, the two laws are equivalent, expressing the same physical law in different ways. The law has been tested extensively, and observations have upheld the law on a scale from 10-16 m to 108 m.
Ancient cultures around the Mediterranean knew that certain objects, such as rods of amber, could be rubbed with cat's fur to attract light objects like feathers and papers. Thales of Miletus made a series of observations on static electricity around 600 BC, from which he believed that friction rendered amber magnetic, in contrast to minerals such as magnetite, which needed no rubbing. Thales was incorrect in believing the attraction was due to a magnetic effect, but later science would prove a link between magnetism and electricity. Electricity would remain little more than an intellectual curiosity for millennia until 1600, when the English scientist William Gilbert made a careful study of electricity and magnetism, distinguishing the lodestone effect from static electricity produced by rubbing amber. He coined the New Latin word electricus ("of amber" or "like amber", from [elektron], the Greek word for "amber") to refer to the property of attracting small objects after being rubbed. This association gave rise to the English words "electric" and "electricity", which made their first appearance in print in Thomas Browne's Pseudodoxia Epidemica of 1646.
Early investigators of the 18th century who suspected that the electrical force diminished with distance as the force of gravity did (i.e., as the inverse square of the distance) included Daniel Bernoulli and Alessandro Volta, both of whom measured the force between plates of a capacitor, and Franz Aepinus who supposed the inverse-square law in 1758.
Based on experiments with electrically charged spheres, Joseph Priestley of England was among the first to propose that electrical force followed an inverse-square law, similar to Newton's law of universal gravitation. However, he did not generalize or elaborate on this. In 1767, he conjectured that the force between charges varied as the inverse square of the distance.
Finally, in 1785, the French physicist Charles-Augustin de Coulomb published his first three reports of electricity and magnetism where he stated his law. This publication was essential to the development of the theory of electromagnetism. He used a torsion balance to study the repulsion and attraction forces of charged particles, and determined that the magnitude of the electric force between two point charges is directly proportional to the product of the charges and inversely proportional to the square of the distance between them.
The torsion balance consists of a bar suspended from its middle by a thin fiber. The fiber acts as a very weak torsion spring. In Coulomb's experiment, the torsion balance was an insulating rod with a metal-coated ball attached to one end, suspended by a silk thread. The ball was charged with a known charge of static electricity, and a second charged ball of the same polarity was brought near it. The two charged balls repelled one another, twisting the fiber through a certain angle, which could be read from a scale on the instrument. By knowing how much force it took to twist the fiber through a given angle, Coulomb was able to calculate the force between the balls and derive his inverse-square proportionality law.
Coulomb's law states that:
The magnitude of the electrostatic force of attraction or repulsion between two point charges is directly proportional to the product of the magnitudes of charges and inversely proportional to the square of the distance between them.
The force is along the straight line joining them. If the two charges have the same sign, the electrostatic force between them is repulsive; if they have different signs, the force between them is attractive.
where ke is Coulomb's constant (ke = ), q1 and q2 are the signed magnitudes of the charges, the scalar r is the distance between the charges, the vector r21 = r1 - r2 is the vectorial distance between the charges, and r?21 = (a unit vector pointing from q2 to q1). The vector form of the equation calculates the force F1 applied on q1 by q2. If r12 is used instead, then the effect on q2 can be found. It can be also calculated using Newton's third law: F2 = -F1.
When the electromagnetic theory is expressed in the International System of Units, force is measured in newtons, charge in coulombs, and distance in meters. Coulomb's constant is given by ke = . The constant ?0 is the vacuum electric permittivity (also known as "electric constant")  in C2?m-2?N-1. It should not be confused with ?r, which is the dimensionless relative permittivity of the material in which the charges are immersed, or with their product ?a = ?0?r, which is called "absolute permittivity of the material" and is still used in electrical engineering.
Coulomb's law and Coulomb's constant can also be interpreted in various terms:
Gaussian units and Lorentz-Heaviside units are both CGS unit systems. Gaussian units are more amenable for microscopic problems such as the electrodynamics of individual electrically charged particles. SI units are more convenient for practical, large-scale phenomena, such as engineering applications.
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An electric field is a vector field that associates to each point in space the Coulomb force experienced by a test charge. In the simplest case, the field is considered to be generated solely by a single source point charge. The strength and direction of the Coulomb force F on a test charge qt depends on the electric field E that it finds itself in, such that F = qtE. If the field is generated by a positive source point charge q, the direction of the electric field points along lines directed radially outwards from it, i.e. in the direction that a positive point test charge qt would move if placed in the field. For a negative point source charge, the direction is radially inwards.
The magnitude of the electric field E can be derived from Coulomb's law. By choosing one of the point charges to be the source, and the other to be the test charge, it follows from Coulomb's law that the magnitude of the electric field E created by a single source point charge q at a certain distance from it r in vacuum is given by:
Coulomb's constant is a proportionality factor that appears in Coulomb's law as well as in other electric-related formulas. The value of this constant is dependent upon the medium that the charged objects are immersed in. Denoted ke, it is also called the electric force constant or electrostatic constant, hence the subscript e.
The exact value of Coulomb's constant in the case of air or vacuum is:
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There are three conditions to be fulfilled for the validity of Coulomb's law:
The last of these is known as the electrostatic approximation. When movement takes place, Einstein's theory of relativity must be taken into consideration, and a result, an extra factor is introduced, which alters the force produced on the two objects. This extra part of the force is called the magnetic force, and is described by magnetic fields. For slow movement, the magnetic force is minimal and Coulomb's law can still be considered approximately correct, but when the charges are moving more quickly in relation to each other, the full electrodynamic rules (incorporating the magnetic force) must be considered.
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where the covariant derivative (in SI units) is:
where is the gauge coupling parameter. By putting the covariant derivative into the lagrangian explicitly, the interaction term (the term involving both and ) is seen to be:
The most basic Feynman diagram for a QED interaction between two fermions is the exchange of a single photon, with no loops. Following the Feynman rules, this therefore contributes two QED vertex factors () to the potential, where Q is the QED-charge operator (Q gives the charge in terms of the electron charge, and hence is exactly -1 for electrons, etc.). For the photon in the diagram, the Feynman rules demand the contribution of one bosonic massless propagator . Ignoring the momentum on the external legs (the fermions), the potential is therefore:
which can be more usefully written as
where is the QED-charge on the ith particle. Recognising the integral as just being a Fourier transform enables the equation to be simplified:
For various reasons, it is more convenient to define the fine-structure constant , and then define . Rearranging these definitions gives:
In natural units (, , and ), . Continuing in SI units, the potential is therefore
Defining , as the macroscopic 'electric charge', makes e the macroscopic 'electric charge' for an electron, and enables the formula to be put into the familiar form of the Coulomb potential:
The force () is therefore :
The derivation makes clear that the force law is only an approximation -- it ignores the momentum of the input and output fermion lines, and ignores all quantum corrections (i.e. the myriad possible diagrams with internal loops).
The Coulomb potential, and its derivation, can be seen as a special case of the Yukawa potential (specifically, the case where the exchanged boson - the photon - has no rest mass).
When it is of interest to know the magnitude of the electrostatic force (and not its direction), it may be easiest to consider a scalar version of the law. The scalar form of Coulomb's Law relates the magnitude and sign of the electrostatic force F acting simultaneously on two point charges q1 and q2 as follows:
where r is the separation distance and ke is Coulomb's constant. If the product q1q2 is positive, the force between the two charges is repulsive; if the product is negative, the force between them is attractive.
Coulomb's law states that the electrostatic force F1 experienced by a charge, q1 at position r1, in the vicinity of another charge, q2 at position r2, in a vacuum is equal to:
where r21 = r1 - r2, the unit vector r?21 = , and ?0 is the electric constant.
The vector form of Coulomb's law is simply the scalar definition of the law with the direction given by the unit vector, r?21, parallel with the line from charge q2 to charge q1. If both charges have the same sign (like charges) then the product q1q2 is positive and the direction of the force on q1 is given by r?21; the charges repel each other. If the charges have opposite signs then the product q1q2 is negative and the direction of the force on q1 is given by -r?21 = r?12; the charges attract each other.
The electrostatic force F2 experienced by q2, according to Newton's third law, is F2 = -F1.
The law of superposition allows Coulomb's law to be extended to include any number of point charges. The force acting on a point charge due to a system of point charges is simply the vector addition of the individual forces acting alone on that point charge due to each one of the charges. The resulting force vector is parallel to the electric field vector at that point, with that point charge removed.
The force F on a small charge q at position r, due to a system of N discrete charges in vacuum is:
where qi and ri are the magnitude and position respectively of the ith charge, R?i is a unit vector in the direction of Ri = r - ri (a vector pointing from charges qi to q).
In this case, the principle of linear superposition is also used. For a continuous charge distribution, an integral over the region containing the charge is equivalent to an infinite summation, treating each infinitesimal element of space as a point charge dq. The distribution of charge is usually linear, surface or volumetric.
For a linear charge distribution (a good approximation for charge in a wire) where ?(r?) gives the charge per unit length at position r?, and dl? is an infinitesimal element of length,
For a surface charge distribution (a good approximation for charge on a plate in a parallel plate capacitor) where ?(r?) gives the charge per unit area at position r?, and dA? is an infinitesimal element of area,
For a volume charge distribution (such as charge within a bulk metal) where ?(r?) gives the charge per unit volume at position r?, and dV? is an infinitesimal element of volume,
The force on a small test charge q? at position r in vacuum is given by the integral over the distribution of charge:
It is possible to verify Coulomb's law with a simple experiment. Consider two small spheres of mass m and same-sign charge q, hanging from two ropes of negligible mass of length l. The forces acting on each sphere are three: the weight mg, the rope tension T and the electric force F.
In the equilibrium state:
Let L1 be the distance between the charged spheres; the repulsion force between them F1, assuming Coulomb's law is correct, is equal to
If we now discharge one of the spheres, and we put it in contact with the charged sphere, each one of them acquires a charge . In the equilibrium state, the distance between the charges will be L2 < L1 and the repulsion force between them will be:
We know that F2 = mg tan ?2. And:
Measuring the angles ?1 and ?2 and the distance between the charges L1 and L2 is sufficient to verify that the equality is true taking into account the experimental error. In practice, angles can be difficult to measure, so if the length of the ropes is sufficiently great, the angles will be small enough to make the following approximation:
Using this approximation, the relationship (6) becomes the much simpler expression:
In this way, the verification is limited to measuring the distance between the charges and check that the division approximates the theoretical value.
Coulomb's law holds even within atoms, correctly describing the force between the positively charged atomic nucleus and each of the negatively charged electrons. This simple law also correctly accounts for the forces that bind atoms together to form molecules and for the forces that bind atoms and molecules together to form solids and liquids. Generally, as the distance between ions increases, the force of attraction, and binding energy, approach zero and ionic bonding is less favorable. As the magnitude of opposing charges increases, energy increases and ionic bonding is more favorable.
Strictly speaking, Gauss's law cannot be derived from Coulomb's law alone, since Coulomb's law gives the electric field due to an individual point charge only. However, Gauss's law can be proven from Coulomb's law if it is assumed, in addition, that the electric field obeys the superposition principle. The superposition principle says that the resulting field is the vector sum of fields generated by each particle (or the integral, if the charges are distributed smoothly in space).
Note that since Coulomb's law only applies to stationary charges, there is no reason to expect Gauss's law to hold for moving charges based on this derivation alone. In fact, Gauss's law does hold for moving charges, and in this respect Gauss's law is more general than Coulomb's law.
Strictly speaking, Coulomb's law cannot be derived from Gauss's law alone, since Gauss's law does not give any information regarding the curl of E (see Helmholtz decomposition and Faraday's law). However, Coulomb's law can be proven from Gauss's law if it is assumed, in addition, that the electric field from a point charge is spherically symmetric (this assumption, like Coulomb's law itself, is exactly true if the charge is stationary, and approximately true if the charge is in motion).
May we not infer from this experiment, that the attraction of electricity is subject to the same laws with that of gravitation, and is therefore according to the squares of the distances; since it is easily demonstrated, that were the earth in the form of a shell, a body in the inside of it would not be attracted to one side more than another?
When making experiments with charged spheres of opposite charge the results were similar, as stated on page 73:
The result of the whole was, that the mutual repulsion of two spheres, electrified positively or negatively, was very nearly in the inverse proportion of the squares of the distances of their centres, or rather in a proportion somewhat greater, approaching to x-2.06.
Nonetheless, on page 74 the author infers that the actual action is related exactly to the inverse duplicate of the distance:
When the experiments were repeated with balls having opposite electricities, and which therefore attracted each other, the results were not altogether so regular and a few irregularities amounted to of the whole; but these anomalies were as often on one side of the medium as on the other. This series of experiments gave a result which deviated as little as the former (or rather less) from the inverse duplicate ratio of the distances; but the deviation was in defect as the other was in excess.
On page 75, the authour compares the electric and gravitational forces:
We therefore think that it may be concluded, that the action between two spheres is exactly in the inverse duplicate ratio of the distance of their centres, and that this difference between the observed attractions and repulsions is owing to some unperceived cause in the form of the experiment.
Therefore we may conclude, that the law of electric attraction and repulsion is similar to that of gravitation, and that each of those forces diminishes in the same proportion that the square of the distance between the particles increases.
We may therefore conclude that the electric attraction and repulsion must be inversely as some power of the distance between that of the 2 + th and that of the 2 - th, and there is no reason to think that it differs at all from the inverse duplicate ratio.
Coulomb also showed that oppositely charged bodies obey an inverse-square law of attraction.
Il résulte donc de ces trois essais, que l'action répulsive que les deux balles électrifées de la même nature d'électricité exercent l'une sur l'autre, suit la raison inverse du carré des distances.
Translation: It follows therefore from these three tests, that the repulsive force that the two balls -- [that were] electrified with the same kind of electricity -- exert on each other, follows the inverse proportion of the square of the distance.