The adiabatic theorem is a concept in quantum mechanics. Its original form, due to Max Born and Vladimir Fock (1928), was stated as follows:
- A physical system remains in its instantaneous eigenstate if a given perturbation is acting on it slowly enough and if there is a gap between the eigenvalue and the rest of the Hamiltonian's spectrum.
In simpler terms, a quantum mechanical system subjected to gradually changing external conditions adapts its functional form, but when subjected to rapidly varying conditions there is insufficient time for the functional form to adapt, so the spatial probability density remains unchanged.
Diabatic vs. adiabatic processes
Diabatic process: Rapidly changing conditions prevent the system from adapting its configuration during the process, hence the spatial probability density remains unchanged. Typically there is no eigenstate of the final Hamiltonian with the same functional form as the initial state. The system ends in a linear combination of states that sum to reproduce the initial probability density.
Adiabatic process: Gradually changing conditions allow the system to adapt its configuration, hence the probability density is modified by the process. If the system starts in an eigenstate of the initial Hamiltonian, it will end in the corresponding eigenstate of the final Hamiltonian.
At some initial time a quantum-mechanical system has an energy given by the Hamiltonian ; the system is in an eigenstate of labelled . Changing conditions modify the Hamiltonian in a continuous manner, resulting in a final Hamiltonian at some later time . The system will evolve according to the time-dependent Schrödinger equation, to reach a final state . The adiabatic theorem states that the modification to the system depends critically on the time during which the modification takes place.
For a truly adiabatic process we require ; in this case the final state will be an eigenstate of the final Hamiltonian , with a modified configuration:
The degree to which a given change approximates an adiabatic process depends on both the energy separation between and adjacent states, and the ratio of the interval to the characteristic time-scale of the evolution of for a time-independent Hamiltonian, , where is the energy of .
Conversely, in the limit we have infinitely rapid, or diabatic passage; the configuration of the state remains unchanged:
The so-called "gap condition" included in Born and Fock's original definition given above refers to a requirement that the spectrum of is discrete and nondegenerate, such that there is no ambiguity in the ordering of the states (one can easily establish which eigenstate of corresponds to ). In 1999 J. E. Avron and A. Elgart reformulated the adiabatic theorem to adapt it to situations without a gap.
Note that the term "adiabatic" is traditionally used in thermodynamics to describe processes without the exchange of heat between system and environment (see adiabatic process). The quantum mechanical definition is closer to the thermodynamical concept of a quasistatic process, and has no direct relation with heat exchange.
As an example, consider a pendulum oscillating in a vertical plane. If the support is moved, the mode of oscillation of the pendulum will change. If the support is moved sufficiently slowly, the motion of the pendulum relative to the support will remain unchanged. A gradual change in external conditions allows the system to adapt, such that it retains its initial character. This is referred to as an "adiabatic process" (a special sense of the word for quantum mechanics).
Quantum harmonic oscillator
Change in the probability density,
, of a ground state quantum harmonic oscillator, due to an adiabatic increase in spring constant.
The classical nature of a pendulum precludes a full description of the effects of the adiabatic theorem. As a further example consider a quantum harmonic oscillator as the spring constant is increased. Classically this is equivalent to increasing the stiffness of a spring; quantum-mechanically the effect is a narrowing of the potential energy curve in the system Hamiltonian.
If is increased adiabatically then the system at time will be in an instantaneous eigenstate of the current Hamiltonian , corresponding to the initial eigenstate of . For the special case of a system like the quantum harmonic oscillator described by a single quantum number, this means the quantum number will remain unchanged. Figure 1 shows how a harmonic oscillator, initially in its ground state, , remains in the ground state as the potential energy curve is compressed; the functional form of the state adapting to the slowly varying conditions.
For a rapidly increased spring constant, the system undergoes a diabatic process in which the system has no time to adapt its functional form to the changing conditions. While the final state must look identical to the initial state for a process occurring over a vanishing time period, there is no eigenstate of the new Hamiltonian, , that resembles the initial state. The final state is composed of a linear superposition of many different eigenstates of which sum to reproduce the form of the initial state.
Avoided curve crossing
An avoided energy-level crossing in a two-level system subjected to an external magnetic field. Note the energies of the diabatic states,
and the eigenvalues
of the Hamiltonian, giving the energies of the eigenstates
(the adiabatic states). (Actually,
should be switched in this picture.)
For a more widely applicable example, consider a 2-level atom subjected to an external magnetic field. The states, labelled and using bra-ket notation, can be thought of as atomic angular-momentum states, each with a particular geometry. For reasons that will become clear these states will henceforth be referred to as the diabatic states. The system wavefunction can be represented as a linear combination of the diabatic states:
With the field absent, the energetic separation of the diabatic states is equal to ; the energy of state increases with increasing magnetic field (a low-field-seeking state), while the energy of state decreases with increasing magnetic field (a high-field-seeking state). Assuming the magnetic-field dependence is linear, the Hamiltonian matrix for the system with the field applied can be written
where is the magnetic moment of the atom, assumed to be the same for the two diabatic states, and is some time-independent coupling between the two states. The diagonal elements are the energies of the diabatic states ( and ), however, as is not a diagonal matrix, it is clear that these states are not eigenstates of the new Hamiltonian that includes the magnetic field contribution.
The eigenvectors of the matrix are the eigenstates of the system, which we will label and , with corresponding eigenvalues
It is important to realise that the eigenvalues and are the only allowed outputs for any individual measurement of the system energy, whereas the diabatic energies and correspond to the expectation values for the energy of the system in the diabatic states and .
Figure 2 shows the dependence of the diabatic and adiabatic energies on the value of the magnetic field; note that for non-zero coupling the eigenvalues of the Hamiltonian cannot be degenerate, and thus we have an avoided crossing. If an atom is initially in state in zero magnetic field (on the red curve, at the extreme left), an adiabatic increase in magnetic field will ensure the system remains in an eigenstate of the Hamiltonian throughout the process (follows the red curve). A diabatic increase in magnetic field will ensure the system follows the diabatic path (the dotted blue line), such that the system undergoes a transition to state . For finite magnetic field slew rates there will be a finite probability of finding the system in either of the two eigenstates. See below for approaches to calculating these probabilities.
These results are extremely important in atomic and molecular physics for control of the energy-state distribution in a population of atoms or molecules.
Proof of the adiabatic theorem
The first proof of this theorem was given by Max Born and Vladimir Fock, in Zeitschrift für Physik 51, 165 (1928). The concept of this theorem deals with the time-dependent Hamiltonian (which might be called a subject of quantum dynamics), where the Hamiltonian changes with time.
For the case of a time-independent Hamiltonian or in a broad sense time-independent potential (subjects of quantum statics) the Schrödinger equation
can be simplified to the time-independent Schrödinger equation
as the general solution of the Schrödinger equation then can be found by the method of separation of variables to give the wavefunction of the form
or, for nth eigenstate only, .
This signifies that a particle that starts from the nth eigenstate remains in the nth eigenstate, simply picking up a phase factor .
In an adiabatic process the Hamiltonian is time-dependent, i.e. the Hamiltonian changes with time (not to be confused with perturbation theory, as here the change in the Hamiltonian is not small; it's huge, although it happens gradually). As the Hamiltonian changes with time, the eigenvalues and the eigenfunctions are time-dependent:
But at any particular instant of time the states still form a complete orthogonal system, i.e.
Notice that the dependence on position is tacitly implied, as the time dependence part will be in more concern. will be considered to be the state of the system at time t, no matter how it depends on its position.
The general solution of time-dependent Schrödinger equation now can be expressed as
- , where
The phase is called the dynamic phase factor. By substitution into the Schrödinger equation, another equation for the variation of the coefficients can be obtained:
The term gives , and so the third term of left side cancels out with the right side, leaving
Now taking the inner product with an arbitrary eigenfunction , the on the left gives , which is 1 only for m = n and otherwise vanishes. The remaining part gives
By calculating the expression for from differentiating the modified time-independent Schrödinger equation 1, this can be written as
This is also exact.
Note that all terms in this expansion have the same order of magnitude , where g is the gap between and the rest of the spectrum, and is the timescale of the evolution. Over macroscopic times of the order of , both therefore seem to give a contribution of order 1. However, unlike the first term, the second term is oscillatory, with an instantaneous frequency never smaller than the gap . It follows that, over long time intervals, the contributions of the second term cancel out, leaving
where is called the geometric phase and is a real number, since is a pure imaginary number. The latter can be easily shown by differentiating the normalization condition .
Putting the obtained expression for the coefficients in the expression for nth eigenstate yields
So, for an adiabatic process, a particle starting from nth eigenstate also remains in that nth eigenstate like it does for the time-independent processes, only picking up a couple of phase factors. The new phase factor can be canceled out by an appropriate choice of gauge for the eigenfunctions. However, if the adiabatic evolution is cyclic, then becomes a gauge-invariant physical quantity, known as the Berry phase.
Deriving conditions for diabatic vs adiabatic passage
This section's factual accuracy is disputed
. (January 2016)
We will now pursue a more rigorous analysis. Making use of bra-ket notation, the state vector of the system at time can be written
where the spatial wavefunction alluded to earlier is the projection of the state vector onto the eigenstates of the position operator
It is instructive to examine the limiting cases, in which is very large (adiabatic, or gradual change) and very small (diabatic, or sudden change).
Consider a system Hamiltonian undergoing continuous change from an initial value , at time , to a final value , at time , where . The evolution of the system can be described in the Schrödinger picture by the time-evolution operator, defined by the integral equation
which is equivalent to the Schrödinger equation.
along with the initial condition . Given knowledge of the system wave function at , the evolution of the system up to a later time can be obtained using
The problem of determining the adiabaticity of a given process is equivalent to establishing the dependence of on .
To determine the validity of the adiabatic approximation for a given process, one can calculate the probability of finding the system in a state other than that in which it started. Using bra-ket notation and using the definition , we have:
We can expand
In the perturbative limit we can take just the first two terms and substitute them into our equation for , recognizing that
is the system Hamiltonian, averaged over the interval , we have:
After expanding the products and making the appropriate cancellations, we are left with:
where is the root mean square deviation of the system Hamiltonian averaged over the interval of interest.
The sudden approximation is valid when (the probability of finding the system in a state other than that in which is started approaches zero), thus the validity condition is given by
which is a statement of the time-energy form of the Heisenberg uncertainty principle.
In the limit we have infinitely rapid, or diabatic passage:
The functional form of the system remains unchanged:
This is sometimes referred to as the sudden approximation. The validity of the approximation for a given process can be characterized by the probability that the state of the system remains unchanged:
In the limit we have infinitely slow, or adiabatic passage. The system evolves, adapting its form to the changing conditions,
If the system is initially in an eigenstate of , after a period it will have passed into the corresponding eigenstate of .
This is referred to as the adiabatic approximation. The validity of the approximation for a given process can be determined from the probability that the final state of the system is different from the initial state:
Calculating adiabatic passage probabilities
The Landau-Zener formula
In 1932 an analytic solution to the problem of calculating adiabatic transition probabilities was published separately by Lev Landau and Clarence Zener, for the special case of a linearly changing perturbation in which the time-varying component does not couple the relevant states (hence the coupling in the diabatic Hamiltonian matrix is independent of time).
The key figure of merit in this approach is the Landau-Zener velocity:
where is the perturbation variable (electric or magnetic field, molecular bond-length, or any other perturbation to the system), and and are the energies of the two diabatic (crossing) states. A large results in a large diabatic transition probability and vice versa.
Using the Landau-Zener formula the probability, , of a diabatic transition is given by
The numerical approach
For a transition involving a nonlinear change in perturbation variable or time-dependent coupling between the diabatic states, the equations of motion for the system dynamics cannot be solved analytically. The diabatic transition probability can still be obtained using one of the wide variety of numerical solution algorithms for ordinary differential equations.
The equations to be solved can be obtained from the time-dependent Schrödinger equation:
where is a vector containing the adiabatic state amplitudes, is the time-dependent adiabatic Hamiltonian, and the overdot represents a time derivative.
Comparison of the initial conditions used with the values of the state amplitudes following the transition can yield the diabatic transition probability. In particular, for a two-state system:
for a system that began with .